Direct Bi3+–Bi3+ contacts mediated by lone pairs in the HP-BiNiO(PO4) polymorph
نویسندگان
چکیده
HP polytype of BiNiO(PO4) (600 °C, 5 GPa) shows the same structural units as AP one but in a denser form. Bi–Bi contacts intra/inter are surprisingly identical due to lone pair electron interaction via sharp σ* bonding at Fermi level.
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ژورنال
عنوان ژورنال: CrystEngComm
سال: 2021
ISSN: ['1466-8033']
DOI: https://doi.org/10.1039/d1ce00802a